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Most Requested Journal Articles 4Q04-Chemistry and Related Science

Following is one of the journal articles most requested by researchers using CAS online services.

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CAS indexed 1 chemical substance from this document. CAS subject entries for this document include: Cycloaddition reaction; Arylation; Arylation catalysts; and 36 additional concepts.

CAPLUS COPYRIGHT 2005 ACS on STN

TITLE:	Enantioselective Palladium-Catalyzed Transformations
AUTHOR(S):	Tietze, Lutz F.; Ila, Hiriyakkanavar; Bell, Hubertus P.
CORPORATE SOURCE:	Institut fuer Organische Chemie, Georg-August-Universitaet, Goettingen, D-37077, Germany
SOURCE:	Chemical Reviews (Washington, DC, United States) (2004), 104(7), 3453-3516 CODEN: CHREAY; ISSN: 0009-2665
PUBLISHER:	American Chemical Society
LANGUAGE:	English

ABSTRACT:
A review. Palladium-catalyzed enantioselective methods were reviewed. These processes are environmentally benign. A disadvantages of palladium-catalyzed transformations are the high price of palladium and usually low turnover nos., which make them too expensive for industrial use. From this review it can be seen that new ligands can be developed which allow the use of chiral palladium catalysts with a turnover no. of 1010, although up to now with low enantioselectivity. A review.

 

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