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Home   •   Spotlight  •  rlist3q07j  •  Most Requested Journal Articles 3Q07-Chemistry and Related Science (6)

Most Requested Journal Articles 3Q07-Chemistry and Related Science

Following is one of the journal articles most requested by researchers using CAS electronic products.

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CAS indexed 68 chemical substances from this document. CAS subject entries for this document include: Amines, reactions; Ethers, preparation; Amines, preparation; and 5 additional concepts.

CAPLUS COPYRIGHT 2007 ACS on STN

TITLE:	Arenes to anilines and aryl ethers by sequential iridium-catalyzed borylation and copper-catalyzed coupling
AUTHOR(S):	Tzschucke, C. Christoph; Murphy, Jaclyn M.; Hartwig, John F.
CORPORATE SOURCE:	Department of Chemistry, Yale University, New Haven, CT, 06520, USA
SOURCE:	Organic Letters (2007), 9(5), 761-764 CODEN: ORLEF7; ISSN: 1523-7060
PUBLISHER:	American Chemical Society
LANGUAGE:	English

ABSTRACT:
N-Alkyl- and N-arylanilines were synthesized from arenes by a two-step sequence of iridium-catalyzed borylation and copper-catalyzed coupling with amines. Diaryl ethers were obtained by a related sequence of arene borylation, followed by coupling with phenols. In particular, 3,5-disubstituted arylamines and aryl ethers were prepd. by initiating this sequence with meta-substituted arenes.