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Most Requested Journal Articles 3Q06-Chemistry and Related Science

Following is one of the journal articles most requested by researchers using CAS electronic products.

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CAS subject entries for this document include: Cycloaddition reaction; Addition reaction; Pericyclic reaction; and 22 additional concepts.

CAPLUS COPYRIGHT 2006 ACS on STN

TITLE:	Organic reactions in aqueous media with a focus on carbon-carbon bond formations. A decade update
AUTHOR(S):	Li, Chao-Jun
CORPORATE SOURCE:	Department of Chemistry, McGill University, Montreal, QC, H3A 2K6, Can.
SOURCE:	Chemical Reviews (Washington, DC, United States) (2005), 105(8), 3095-3165 CODEN: CHREAY; ISSN: 0009-2665
PUBLISHER:	American Chemical Society
LANGUAGE:	English

ABSTRACT:
A review. The following topics are discussed: reaction of alkanes (carboxylation), reaction of alkenes (electrophilic addns., radical reactions, carbene reactions, transition-metal-catalyzed addns., olefin metathesis, and cycloaddn. reactions), reaction of alkynes (dimerizations; reactions with org. halides, carbonyl compds., and imines; conjugate addn.; nucleophilic and electrophilic addns. to the C.tplbond.C triple bond; hydrocarboxylation; hydrophosphinylation; hydrometalation/coupling; Pauson-Khand-type reactions; and reductive coupling) reaction of arom. compds. (electrophilic and radical substitutions, oxidative coupling, and photochem. reactions), reaction of carbonyl compds. (nucleophilic addns., pinacol coupling, and Wittig reactions), reactions of .alpha.,.beta.-unsatd. carbonyl compds. (conjugate addns., Baylis-Hillman reactions, and reductive coupling), reaction of amines, imines, and nitriles (nucleophilic addns., reductive coupling), reaction of org. halides (nucleophilic substitution; reductive coupling: Wurtz-type and Ullmann-type coupling, carbonylation, Heck coupling, Suzuki coupling, Stille coupling, and the Trost-Tsuji reaction), and pericyclic reactions (Diels-Alder reactions, hetero-Diels-Alder reactions, Alder-ene reactions, 1,3-dipolar cycloaddns., sigmatropic rearrangements: Claisen and Cope rearrangements, and photochem. cycloaddns.).