Following is one of the journal articles most requested by researchers using CAS electronic products.
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CAS indexed 76 chemical substances from this document.
CAS subject entries for this document include: Amines, preparation; Azides; Reaction mechanism; and 2 additional concepts. | |
CAPLUS COPYRIGHT 2007 ACS on STN
| TITLE:
| Radical Reduction of Aromatic Azides to Amines with Triethylsilane |
| AUTHOR(S):
| Benati, Luisa; Bencivenni, Giorgio; Leardini, Rino; Minozzi, Matteo; Nanni, Daniele; Scialpi, Rosanna; Spagnolo, Piero; Zanardi, Giuseppe |
| CORPORATE SOURCE:
| Dipartimento di Chimica Organica "A. Mangini", Universita di Bologna, Bologna, I-40136, Italy |
| SOURCE:
| Journal of Organic Chemistry (2006), 71(15), 5822-5825 CODEN: JOCEAH; ISSN: 0022-3263 |
| PUBLISHER:
| American Chemical Society |
| LANGUAGE:
| English |
ABSTRACT:Arom. azides are inert toward triethylsilane under thermal conditions in the presence of a radical initiator, but in the presence of addnl. catalytic amts. of tert-dodecanethiol, they afford anilinosilanes and thence the corresponding anilines in virtually quant. yields.
Updated 5/15/2007 1:14:38 PM
