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CAS indexed 104 chemical substances from this document.
CAS subject entries for this document include: Addition reaction; Acids, preparation; Group IIIA element compounds. | |
CAPLUS COPYRIGHT 2004 ACS on STN
| TITLE:
| Transition metal catalyzed preparation of boronate esters using boron reagents and hydrocarbons |
| INVENTOR(S):
| Smith, Milton R., III |
| PATENT ASSIGNEE(S):
| Michigan State University, USA |
| SOURCE:
| PCT Int. Appl., 152 pp. CODEN: PIXXD2 |
| LANGUAGE:
| English |
PATENT INFORMATION: PATENT NO. KIND DATE APPLICATION NO. DATE
--------------- ---- -------- --------------- --------
WO 2003006158 A2 20030123 WO 2002-US23302 20020713
WO 2003006158 A3 20030403
W: AE, AG, AL, AM, AT, AU, AZ, BA, BB, BG, BR, BY, BZ, CA, CH, CN,
CO, CR, CU, CZ, DE, DK, DM, DZ, EC, EE, ES, FI, GB, GD, GE, GH,
GM, HR, HU, ID, IL, IN, IS, JP, KE, KG, KP, KR, KZ, LC, LK, LR,
LS, LT, LU, LV, MA, MD, MG, MK, MN, MW, MX, MZ, NO, NZ, OM, PH,
PL, PT, RO, RU, SD, SE, SG, SI, SK, SL, TJ, TM, TN, TR, TT, TZ,
UA, UG, UZ, VN, YU, ZA, ZM, ZW, AM, AZ, BY, KG, KZ, MD, RU, TJ, TM
RW: GH, GM, KE, LS, MW, MZ, SD, SL, SZ, TZ, UG, ZM, ZW, AT, BE, BG,
CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL,
PT, SE, SK, TR, BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, ML, MR,
NE, SN, TD, TG
US 2003109380 A1 20030612 US 2002-194809 20020712
ABSTRACT:
A process for producing a ring-substituted arene borane which comprises reacting a ring-substituted arene with an HB org. compd. in the presence of a catalytically effective amt. of an iridium or rhodium complex with three or more substituents, excluding hydrogen, bonded to the iridium or rhodium and a phosphorus org. ligand, which is at least in part bonded to the iridium or rhodium, to form the ring-substituted arene borane. Also provided are catalytic compds. for catalyzing the process comprising an iridium or rhodium complex with three or substituents, excluding hydrogen, bonded to the iridium or rhodium and optionally, a phosphorus org. ligand, which is at least in part bonded to the iridium or rhodium. For example, (indenyl)Ir(COD) and dppe were dissolved with HBPin and the soln. was added to 1,3-bis(trifluoromethyl)benzene to give 78% 1,3,5-C6H3(CF3)2(BPin).
Updated 5/4/2007 7:45:58 AM
